Xenon tetroxide

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Template:Chembox SolubilityInWater
Xenon tetroxide
IUPAC name xenon tetraoxide
xenon(VIII) oxide
Structure
Molecular shape Tetrahedral[1]
Dipole moment 0 D
Properties
XeO4
Molar mass 195.29 g mol−1
Appearance Yellow solid below −36°C
Density ? g cm−3, solid
Melting point
Boiling point
Thermochemistry
Std enthalpy of
formation
ΔfHo298
? kJ mol−1
Standard molar
entropy
So298
? J.K−1.mol−1
Hazards
EU classification {{{value}}}
Related compounds
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Xenon tetroxide (molecular formula XeO4) is a yellow crystalline solid that is stable below −35.9 °C.[2][3] The xenon atom has an oxidation state of +8 and oxygen of −2. All eight valence shell electrons of xenon are involved, making it an unstable compound. Above -35.9°C it explodes to give xenon and oxygen gas. Oxygen is the only element that can bring xenon up to its highest oxidation state; even fluorine can only give XeF6, probably for steric reasons. Xenon tetroxide dissolves in water[citation needed] to give perxenic acid, and in alkalis[citation needed] to give the perxenate ion.

Another known oxide is xenon trioxide. The dioxide remains elusive and only the XeOO+ cation has been identified by infrared spectroscopy in solid argon[4].

Reactions

A spontaneous explosion occurs at temperature above −35.9 °C , with ΔH = -643 kJ/mol.

XeO4 → Xe + 2 O2

The two other short lived xenon compounds with an oxidation state of +8 are accessible by the reaction of xenon tetroxide with xenon hexafluoride. XeO3F2 and XeO2F4 can be detected with mass spectroscopy.

Synthesis

All syntheses start from the perxenates, which are accessible from the xenates through two methods. One is disproportionation of xenates to perxenates and xenon:

2 XeO42− → XeO64− + Xe + O2.

The other is oxidation of the xenates with ozone:

2 XeO42− + 4 e- + 2 O3 → 2 XeO64- + 2 O2.

Barium perxenate is reacted with sulfuric acid and the unstable perxenic acid is dehydrated to give xenon tetroxide:

Ba2XeO6 + 2 H2SO4 → 2 BaSO4 + (H4XeO6 → 2 H2O + XeO4).

The unstable perxenic acid slowly undergoes a disproportionation reaction to the xenic acid and oxygen:

H4XeO6 → 1/2 O2 + H2XeO4 + H2O.

References

  1. G. Gundersen, K. Hedberg, J. L.Huston (1970). "Molecular Structure of Xenon Tetroxide, XeO4". J. Chem. Phys. 52: 812–815. doi:10.1063/1.1673060.
  2. H.Selig , J. G. Malm , H. H. Claassen , C. L. Chernick , J. L. Huston (1964). "Xenon tetroxide -Preparation + Some Properties". Science. 143: 1322. doi:10.1126/science.143.3612.1322.
  3. J. L. Huston, M. H. Studier, E.N. Sloth (1964). "Xenon tetroxide - Mass Spectrum". Science. 143: 1162. doi:10.1126/science.143.3611.1161-a.
  4. M. Zhou, Y. Zhao, Y. Gong, J. Li (2006). "Formation and Characterization of the XeOO+ Cation in Solid Argon". J. Am. Chem. Soc. 128: 2504–2505. doi:10.1021/ja055650n.
  1. Lide, D. R. (ed.) (2002). CRC Handbook of Chemistry and Physics (83rd ed. ed.). Boca Raton, FL: CRC Press. Unknown parameter |ibsn= ignored (help)

cs:Oxid xenoničelý de:Xenon(VIII)-oxid


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